6 research outputs found

    Spin-strain coupling in a 3-D transition metal oxides

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    ab-initio Hartree Fock (HF), density functional theory (DFT) and hybrid potentials were employed to compute the optimized lattice parameters and elastic properties of perovskite 3-d transition metal oxides. The optimized lattice parameters and elastic properties are interdependent in these materials. An interaction is observed between the electronic charge, spin and lattice degrees of freedom in 3-d transition metal oxides. The coupling between the electronic charge, spin and lattice structures originates due to localization of d-atomic orbitals. The coupling between the electronic charge, spin and crystalline lattice also contributes in the ferroelectric and ferromagnetic properties in perovskites. The cubic and tetragonal crystalline structures of perovskite transition metal oxides of ABO3 are studied. The electronic structure and the physics of 3-d perovskite materials is complex and less well considered. Moreover, the novelty of the electronic structure and properties of these perovskites transition metal oxides exceeds the challenge offered by their complex crystalline structures. To achieve the objective of understanding the structure and property relationship of these materials the first-principle computational method is employed. CRYSTAL09 code is employed for computing crystalline structure, elastic, ferromagnetic and other electronic properties. Second-order elastic constants (SOEC) and bulk moduli (B) are computed in an automated process by employing ELASTCON (elastic constants) and EOS (equation of state) programs in CRYSTAL09 code. ELASTCON, EOS and other computational algorithms are utilized to determine the elastic properties of tetragonal BaTiO3, rutile TiO2, cubic and tetragonal BaFeO3 and the ferromagentic properties of 3-d transition metal oxides. Multiple methods are employed to crosscheck the consistency of our computational results. Computational results have motivated us to explore the ferromagnetic properties of 3-d transition metal oxides. Billyscript and CRYSTAL09 code are employed to compute the optimized geometry of the cubic and tetragonal crystalline structure of transition metal oxides of Sc to Cu. Cubic crystalline structure is initially chosen to determine the effect of lattice strains on ferromagnetism due to the spin angular momentum of an electron. The 3-d transition metals and their oxides are challenging as the basis functions and potentials are not fully developed to address the complex physics of the transition metals. Moreover, perovskite crystalline structures are extremely challenging with respect to the quality of computations as the latter requires the well established methods. Ferroelectric and ferromagnetic properties of bulk, surfaces and interfaces are explored by employing CRYSTAL09 code. In our computations done on cubic TMOs of Sc-Fe it is observed that there is a coupling between the crystalline structure and FM/AFM spin polarization. Strained crystalline structures of 3-d transition metal oxides are subjected to changes in the electromagnetic and electronic properties. The electronic structure and properties of bulk, composites, surfaces of 3-d transition metal oxides are computed successfully

    A FUZZY BASED PARAMETRIC MONITORING AND CONTROL ALGORITHM FOR DISTINCTIVE LOADS TO ENHANCE THE STABILITY IN RURAL ISLANDED MICROGRIDS

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    Effective monitoring and control of isolated rural microgrid in the developing world is challenging. The modern communication and monitoring is difficult to handle in such communities due to a complicated approach to the area, lack of modern facilities and unavailability of skilled manpower. Implementation of a microgrid in such areas using intermittent renewable sources and limited storage is challenging. Uncontrolled load consumption leads to the system-wide outages due to prolonged storage utilization in peak hours and is referred here as battery storage stress hours (BSSH). This research is focused to study and analyze the behavior of parametric load monitoring and control algorithm that could control the distinctive load of the microgrid during BSSH. In the proposed algorithm, the residential loads are distinctively controlled while utilizing the three locally available parameters that are the state of the charge of storage, solar irradiations and ambient temperature. In other words, the natural parameter variations have been uniquely utilized as a monitoring tool for load control. The fuzzy controller takes a decision for the activation or deactivation of any load based on the three parameters variation ranges. It is observed from the simulation and experimental results that while only utilizing locally available parameters the effective load control is possible

    Spin-strain coupling in 3-d transition metal oxides

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    ab-initio Hartree Fock (HF), density functional theory (DFT) and hybrid potentials were employed to compute the optimized lattice parameters and elastic properties of perovskite 3-d transition metal oxides. The optimized lattice parameters and elastic properties are interdependent in these materials. An interaction is observed between the electronic charge, spin and lattice degrees of freedom in 3-d transition metal oxides. The coupling between the electronic charge, spin and lattice structures originates due to localization of d-atomic orbitals. The coupling between the electronic charge, spin and crystalline lattice also contributes in the ferroelectric and ferromagnetic properties in perovskites. The cubic and tetragonal crystalline structures of perovskite transition metal oxides of ABO3 are studied. The electronic structure and the physics of 3-d perovskite materials is complex and less well considered. Moreover, the novelty of the electronic structure and properties of these perovskites transition metal oxides exceeds the challenge offered by their complex crystalline structures. To achieve the objective of understanding the structure and property relationship of these materials the first-principle computational method is employed. CRYSTAL09 code is employed for computing crystalline structure, elastic, ferromagnetic and other electronic properties. Second-order elastic constants (SOEC) and bulk moduli (B) are computed in an automated process by employing ELASTCON (elastic constants) and EOS (equation of state) programs in CRYSTAL09 code. ELASTCON, EOS and other computational algorithms are utilized to determine the elastic properties of tetragonal BaT iO3, rutile TiO 2, cubic and tetragonal BaFeO3 and the ferromagentic properties of 3-d transition metal oxides. Multiple methods are employed to crosscheck the consistency of our computational results. Computational results have motivated us to explore the ferromagnetic properties of 3-d transition metal oxides. Billyscript and CRYSTAL09 code are employed to compute the optimized geometry of the cubic and tetragonal crystalline structure of transition metal oxides of Sc to Cu. Cubic crystalline structure is initially chosen to determine the effect of lattice strains on ferromagnetism due to the spin angular momentum of an electron. The 3-d transition metals and their oxides are challenging as the basis functions and potentials are not fully developed to address the complex physics of the transition metals. Moreover, perovskite crystalline structures are extremely challenging with respect to the quality of computations as the latter requires the well established methods. Ferroelectric and ferromagnetic properties of bulk, surfaces and interfaces are explored by employing CRYSTAL09 code. In our computations done on cubic TMOs of Sc-Fe it is observed that there is a coupling between the crystalline structure and FM/AFM spin polarization. Strained crystalline structures of 3-d transition metal oxides are subjected to changes in the electromagnetic and electronic properties. The electronic structure and properties of bulk, composites, surfaces of 3-d transition metal oxides are computed successfully

    Power Efficient Fully Differential Bulk Driven OTA for Portable Biomedical Application

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    This paper presents a power efficient, bulk driven, source degenerated fully differential operational transconductance amplifier (OTA), operating in the subthreshold region. The input part of the OTA consists of a bulk driven source degenerated differential pair and cross coupled transistors to improve the linearity of OTA. It consists of a bulk driven pair to reduce the supply voltage and to improve the linearity. The proposed fully differential OTA has utilized self-cascode current mirror loads which increases the output impedance and hence the overall intrinsic gain. A subthreshold region is adopted to reduce the power consumption of the circuit. For a 200 mVpp sinusoidal input at 100 Hz, a total harmonic distortion (THD) of −58.56 dB is achieved. The gain, gain bandwidth (GBW), phase margin (PM) and gain margin (GM) values obtained were 48.4 dB, 3.1 KHz, 80° and 19.01 dB, respectively. The common mode rejection ratio (CMRR), power supply rejection ratio (PSRR) and slew rate +/− values were 146.3 dB, 83 dB and 99.56/100 V/ms, respectively. The circuit is capable of operating under a supply voltage of 0.8 V with a power consumption of 59.04 nW, which proves that the circuit is suitable for portable biomedical devices. The proposed circuit is simulated in CADENCE environment virtuoso using LFoundry 150 nm Complementary metal oxide semiconductor (CMOS) process technology
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